Chemical kinetics Chemical kinetics, also known as reaction kinetics, is the study of rates of chemical processes. Chemical kinetics includes investigations of how different experimental conditions can influence the speed of a chemical reaction and yield information about the reaction's mechanism and transition states, as well as the construction of mathematical models that can describe the characteristics of a chemical reaction. The respective second-order rate constants for these reactions which were deduced. Methylrhenium Trioxide Revisited: Mechanisms for Nonredox Oxygen. Cungen Zhang, Ilia A. Guzei, and James H. Kinetics and Mechanism of the Methyltrioxorhenium-Catalyzed Sulfoxidation of Thioketones and Sulfines.

This Perspective presents a personal overview of the current status of the theory of chemical kinetics and mechanisms for complex processes. We attempt to assess the status of the field for reactions in the gas phase, at gas–solid interfaces, in liquid solutions, in enzymes, and for protein folding. Some unifying concepts such as potential energy surfaces, free energy, master equations, and reaction coordinates occur in more than one area.

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We hope this Perspective will be useful for highlighting recent advances and for identifying important areas for future research.

• • • Abstract One of the important reasons why chemists study rates of chemical reactions is a practical one. They want to determine the rate at which a reaction mixture approaches the state of its equilibrium, yielding a certain reaction product. This rate can be enhanced by changing the concentration of reactants and the pressure, by temperature increase, or by various catalysts. A more sophisticated reason, which is presently of our primary interest, is the study of reaction mechanisms, that is, the determination of those elementary reaction steps which finally lead to the reaction product.