An unexpected borylation of organic halides with a silyborane in the presence of an alkoxy base has been observed. This formal nucleophilic boryl substitution can be applied to a broad range of substrates with high functional group compatibility. Even sterically hindered aryl bromides afforded the corresponding boryl compounds in high yields.

Slavic and East European Collections, The New York Public Library. 'Polotentse o dvukh raznykh kontsakh Kargopol'skoi uezda Olonetskoi gub. Izobrazhaet lev zveria i ptitsu dvuglavago orla. Ispolneno po kholstu tsvetnymi sherstiami.' The New York Public Library Digital Collections. Pharmacogenetics of Carboxylesterase 1 Katriina Tarkiainen ACADEMIC DISSERTATION To be presented, with the permission of the Faculty of Medicine of the University of Helsinki, for public examination in Lecture Hall 3 of Biomedicum Helsinki 1, Haartmaninkatu 8, on 9 June 2017, at 12 noon.

Preliminary mechanistic studies indicated that this boryl substitution is promoted by neither transition-metal contamination nor a radical-mediated process.

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